|
|
H2O + (R)-3-((R)-3-hydroxybutanoyloxy)butanoate <=> H+ + (R)-3-hydroxybutanoate
|
3.1.1.22
hydroxybutyrate-dimer hydrolase
3.1.1.75
poly(3-hydroxybutyrate) depolymerase
|
–
–
|
K
|
|
BRENDA:
BR10649
KEGG:
R00048
MetaCyc:
HYDROXYBUTYRATE-DIMER-HYDROLASE-RXN
SABIO-RK:
638
|
|
|
|
(R)-3-hydroxybutanoate + NAD+ <=> acetoacetate + NADH + H+
|
1.1.1.30
3-hydroxybutyrate dehydrogenase
|
–
|
MK
|
|
BRENDA:
BR29293
KEGG:
R01361
MetaCyc:
3-HYDROXYBUTYRATE-DEHYDROGENASE-RXN
SABIO-RK:
1565
|
|
|
|
(3R)-hydroxybutyryl-CoA + H2O <=> (R)-3-hydroxybutanoate + CoA + H+
|
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.4
3-hydroxyisobutyryl-CoA hydrolase
|
–
–
–
|
M
|
|
BRENDA:
BS360747
MetaCyc:
RXN-14255
SABIO-RK:
12736
|
|
|
|
poly(3-hydroxybutanoate)n + H2O <=> poly(3-hydroxybutanoate)n + (R)-3-hydroxybutanoate
|
3.1.1.75
poly(3-hydroxybutyrate) depolymerase
|
–
|
|
|
MetaCyc:
3.1.1.75-RXN
|
|
|
|
N-3-hydroxybutanoyl-L-homoserine_lactone + H2O <=> L-homoserine_lactone + (R)-3-hydroxybutanoate
|
3.5.1.97
acyl-homoserine-lactone acylase
|
–
|
|
|
MetaCyc:
RXN-10041
|
|
|
|
(R)-3-((R)-3-hydroxybutanoyloxy)11butanoate + H2O <=> (R)-3-hydroxybutanoate
|
3.1.1.22
hydroxybutyrate-dimer hydrolase
|
–
|
|
|
BRENDA:
BS64346
|
|
|
|
(R)-3-((R)-3-hydroxybutanoyloxy)7butanoate + H2O <=> (R)-3-hydroxybutanoate
|
3.1.1.22
hydroxybutyrate-dimer hydrolase
|
–
|
|
|
BRENDA:
BS64345
|
|
|
|
(S)-3-((R)-3-hydroxybutanoyloxy)butanoate + H2O <=> (R)-3-hydroxybutanoate + L-3-hydroxybutyrate
|
3.1.1.22
hydroxybutyrate-dimer hydrolase
|
–
|
|
|
BRENDA:
BS64341
|
|
|
|
(R)-3-((R)-3-hydroxybutanoyloxy)2butanoate + H2O <=> (R)-3-hydroxybutanoate
|
3.1.1.22
hydroxybutyrate-dimer hydrolase
|
–
|
|
|
BRENDA:
BS64342
|
|
|
|
(R)-3-((R)-3-hydroxybutanoyloxy)3butanoate + H2O <=> (R)-3-hydroxybutanoate
|
3.1.1.22
hydroxybutyrate-dimer hydrolase
|
–
|
|
|
BRENDA:
BS64343
|
|
|
|
[(R)-3-hydroxybutanoate]5 + H2O <=> (R)-3-hydroxybutanoate
|
3.1.1.22
hydroxybutyrate-dimer hydrolase
|
–
|
|
|
BRENDA:
BS64344
|
|
|
|
methyl_(3R)-3-[[(3''R)-3''-hydroxybutanoyl]oxy]butanoate + H2O <=> (R)-3-hydroxybutanoate + methyl-(R)-3-hydroxybutanoate + (R)-3-[[(3''R)-3''-hydroxybutanoyl]oxy]butanoic_acid
|
3.1.1.75
poly(3-hydroxybutyrate) depolymerase
|
–
|
|
|
BRENDA:
BS139722
|
|
|
|
(R)-3-((S)-3-hydroxybutanoyloxy)butanoate + H2O <=> (R)-3-hydroxybutanoate + L-3-hydroxybutyrate
|
3.1.1.22
hydroxybutyrate-dimer hydrolase
|
–
|
|
|
BRENDA:
BS64340
|
|
|
|
methyl_(3R)-3-[[(3''R)-3''-[[(3''''R)-3''''-[[(3''''''R)-3''''''-hydroxybutanoyl]oxy]butanoyl]oxy]butanoyl]oxy]butanoate + H2O <=> (R)-3-hydroxybutanoate + methyl-(R)-3-hydroxybutanoate + (R)-3-[[(3''R)-3''-hydroxybutanoyl]oxy]butanoic_acid + methyl_(3R)-3-[[(3''R)-3''-hydroxybutanoyl]oxy]butanoate + (R)-3-[[(3''R)-3''-[[(3''''R)-3''''-hydroxybutanoyl]oxy]butanoyl]oxy]butanoic_acid + methyl_(3R)-3-[[(3''R)-3''-[[(3''''R)-3''''-[[(3''''''R)-3''''''-hydroxybutanoyl]oxy]butanoyl]oxy]butanoyl]oxy]butanoate
|
3.1.1.75
poly(3-hydroxybutyrate) depolymerase
|
–
|
|
|
BRENDA:
BS139726
|
|
|
|
(R)-3-hydroxybutanoate + NADH + H+ <=> acetoacetate + NAD+
|
1.1.1.30
3-hydroxybutyrate dehydrogenase
|
–
|
|
|
BRENDA:
BS394975
|
|
|
|
(R)-3-hydroxybutanoate + NADP+ <=> acetoacetate + NADPH
|
1.1.1.276
serine 3-dehydrogenase (NADP+)
1.1.1.30
3-hydroxybutyrate dehydrogenase
|
–
–
|
|
|
BRENDA:
BS355790
|
|
|
|
methyl_(3R)-3-[[(3''R)-3''-[[(3''''R)-3''''-hydroxybutanoyl]oxy]butanoyl]oxy]butanoate + H2O <=> (R)-3-hydroxybutanoate + methyl-(R)-3-hydroxybutanoate + (R)-3-[[(3''R)-3''-hydroxybutanoyl]oxy]butanoic_acid + methyl_(3R)-3-[[(3''R)-3''-hydroxybutanoyl]oxy]butanoate + (R)-3-[[(3''R)-3''-[[(3''''R)-3''''-hydroxybutanoyl]oxy]butanoyl]oxy]butanoic_acid
|
3.1.1.75
poly(3-hydroxybutyrate) depolymerase
|
–
|
|
|
BRENDA:
BS139723
|
|
|
|
(R)-3-hydroxybutanoate + 3-acetylpyridine_adenine_dinucleotide <=> acetoacetate + reduced_acetylpyridine_adenine_dinucleotide
|
1.1.1.30
3-hydroxybutyrate dehydrogenase
|
–
|
|
|
BRENDA:
BS188035
|
|
|
|
poly(3-hydroxybutanoate)n + n H2O <=> poly_(3-hydroxybutanoate)_n-1 + (R)-3-hydroxybutanoate
|
3.1.1.75
poly(3-hydroxybutyrate) depolymerase
|
–
|
|
|
BRENDA:
BS448000
|
|